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European Facility For Airborne Research Feb. 23, 2018, 07:56

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Description
Title OH and HO2 chemistry during NAMBLEX: roles of oxygenates, halogen oxides and heterogeneous uptake
Type Publication
Abstract:

Several zero-dimensional box-models with different levels of chemical complexity, based on the Master Chemical Mechanism (MCM), have been used to study the chemistry of OH and HO2 in a coastal environment in the Northern Hemisphere. The models were constrained to and compared with measurements made during the NAMBLEX campaign (Mace Head, Ireland) in summer 2002.
The base models, which were constrained to measured CO, CH4 and NMHCs, were able to reproduce [OH] within 25%, but overestimated [HO2] by about a factor of 2. Agreement was improved when the models were constrained to oxygenated compounds (acetaldehyde, methanol and acetone), highlighting their importance for the radical budget. When the models were constrained to measured halogen monoxides (IO, BrO) and used a more detailed, measurements-based, treatment to describe the heterogeneous uptake, modelled [OH] increased by up to 15% and [HO2] decreased by up to 30%. The actual impact of halogen monoxides on the modelled concentrations of HOx was dependant on the uptake coefficients used for HOI, HOBr and HO2. Better agreement, within the combined uncertainties of the measurements and of the model, was achieved when using high uptake coefficients for HO2 and HOI (γHO2=1, γHOI=0.6).
A rate of production and destruction analysis of the models allowed a detailed study of OH and HO2 chemistry under the conditions encountered during NAMBLEX, showing the importance of oxygenates and of XO (where X=I, Br) as co-reactants for OH and HO2 and of HOX photolysis as a source for OH.

Available from http://www.atmos-chem-phys.net/6/1135/2006/
Author
HEARD Dwayne
LEWIS Alastair
MONKS Paul
WILLIAMS Paul
To see the full author list, please click on the link
Reference
Journal Atmospheric Chemistry and Physics
Volume 5
Pages 10947-1099
Year 2005
Times cited 0
Institute country United Kingdom
Type of science
  • Gas chemistry
Field of science
  • Troposphere
File details
Added Feb. 13, 2006, 00:00
Last update Aug. 8, 2017, 09:56
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